Synthesis of a new type of alkene metal complex using face-capping thione-alkene ligands.
نویسندگان
چکیده
A series of complexes of novel chelating thione-alkene S(η(2)-C[double bond, length as m-dash]C)S tridentate ligands bound to late transition metals (Ir, Rh, Pd) were isolated and characterised. Counter-anions play an important role in the binding of the alkene moiety to the metals. Different solvents were observed to affect the stability of the rhodium complexes.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 19 شماره
صفحات -
تاریخ انتشار 2015